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Abstract The southeastern Atlantic Ocean is a crucial yet understudied region for the ocean absorption of anthropogenic carbon (Canth). Data from the A12 (2020) and A13.5 (2010) cruises offer an opportunity to examine changes in dissolved inorganic carbon (DIC), its stable isotope (δ13C), and Canthover the past decade within a limited region (1∼3°E, 32∼42°S). For the decade of 2010–2020, Canthinvasion was observed from the sea surface down to 1,200 m based on both DIC and δ13C data. The mean Canthincrease rate (1.08 ± 0.26 mol m−2 yr−1) during this period accelerated from 0.87 ± 0.05 mol m−2 yr−1during the previous period (1983/84–2010). The δ13C‐based Canthincrease closely matches the DIC‐based estimation below 500 m but is 26% higher in the upper ocean. This discrepancy is likely due to δ13C's longer air‐sea exchange timescale, seasonal variability in the upper ocean, and the chosen ratio of anthropogenically induced changes in δ13C and DIC. Finally, column inventory changes based on the two methods also exhibit very similar mean Canthuptake rates. The paired DIC concentration and stable isotope dataset may enhance our ability to constrain Canthaccumulation and its controlling mechanisms in the ocean.more » « less
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Hemorrhage is a prime cause of death in civilian and military traumatic injuries, whereby a significant proportion of death and complications occur prior to paramedic arrival and hospital resuscitation. Hence, it is crucial to develop hemostatic materials that are able to be applied by simple processes and allow control over bleeding by inducing rapid hemostasis, non-invasively, until subjects receive necessary medical care. This tutorial review discusses recent advances in synthesis and fabrication of degradable hemostatic nanomaterials and nanocomposites. Control of assembly and fine-tuning of composition of absorbable ( i.e. , degradable) hemostatic supramolecular structures and nanoconstructs have afforded the development of smart devices and scaffolds capable of efficiently controlling bleeding while degrading over time, thereby reducing surgical operation times and hospitalization duration. The nanoconstructs that are highlighted have demonstrated hemostatic efficiency pre-clinically in animal models, while also sharing characteristics of degradability, bioabsorbability and presence of nano-assemblies within their compositions.more » « less
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Transition metal dichalcogenides (TMDs) have attracted much interest in recent years due to their emerging material properties. In monolayer TMDs, such as MoS2, extreme quantum confinement is achieved in the monolayer limit. Although monolayer TMDs represent an ideal platform to explore excitonic physics using ultrafast spectroscopy, this exploration is currently limited by confusion regarding the origin of certain spectral features, including the below-bandgap PIA feature observed in pump-probe experiments. In this work, we document an absence of PIA features immediately after photoexcitation, indicating a lack of strong optically-induced biexciton formation. Below-bandgap PIA features are observed to grow in with a time constant of 110 ± 10 fs, indicative of other factors responsible for their origin. These results indicate that optically-induced biexciton formation is most likely not responsible for the previously observed PIA features in MoS2 monolayers.more » « less
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Abstract The South Atlantic Ocean is an important region for anthropogenic CO2(Canth) uptake and storage in the world ocean, yet is less studied. Here, after an extensive sensitivity test and method comparison, we applied an extended multiple linear regression method with six characteristic water masses to estimate Canthchange or increase (ΔCanth) between 1980s and 2010s in the South Atlantic Ocean using two meridional transects (A16S and A13.5) and one zonal transect (A10). Over a period of about 25 years, the basin‐wide ΔCanthwas 3.86 ± 0.14 Pg C decade−1. The two basins flanking the Mid‐Atlantic Ridge had different meridional patterns of ΔCanth, yielding an average depth‐integrated ΔCanthin the top 2000 m of 0.91 ± 0.25 mol m−2 yr−1along A16S on the west and 0.57 ± 0.22 mol m−2 yr−1along A13.5 on the east. The west‐east basin ΔCanthcontrasts were most prominent in the tropical region (0–20°S) in the Surface Water (SW), approximately from equator to 35°S in the Subantarctic Mode Water (Subantarctic Mode Water (SAMW)), and all latitudes in the Antarctic Intermediate Water (AAIW). Less ΔCanthin the eastern basin than the western basin was caused by weaker ventilation driven by SAMW and AAIW formation and subduction and stronger Antarctic Bottom Water (AABW) formation in the former than the latter. In addition to the spatial heterogeneity, Canthincrease rates accelerated from the 1990s to the 2000s, consistent with the overall increase in air‐sea CO2exchange in the South Atlantic Ocean.more » « less
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